3 occurrences across the corpus

King James Version

Daniel 5:31

And Darius the Median took the kingdom, being about threescore and two years old.

OT Pseudepigrapha

The Sibylline Oracles 11:80

And then to thee, O Median land, a man

The Sibylline Oracles 11:85

Thou Median nation; thou shalt afterwards