2 occurrences across the corpus

King James Version

Deuteronomy 32:13

He made him ride on the high places of the earth, that he might eat the increase of the fields; and he made him to suck honey out of the rock, and oil out of the flinty rock;

KJV Apocrypha (Catholic Deuterocanon)

Wisdom of Solomon 11:4

When they were thirsty, they called upon thee, and water was given them out of the flinty rock, and their thirst was quenched out of the hard stone.